Organometallic Compounds [electronic resource] : Volume Two: The Transition Elements / by M. L. Green.

Erişim Adresi
Link
ISBN
9789401168939
Dil Kodu
İngilizce
Yer Numarası
DK/13791
Yazar
Green, M. L.
Basım Bildirimi
1st ed. 1968.
Yayın Bilgisi
Dordrecht : Springer Netherlands : Imprint: Springer, 1968.
Fiziksel Niteleme
XIII, 376 p. 138 illus. online resource.
İçindekiler Notu
to Volume Two -- Classification -- The 18-electron rule -- 1. Two-Electron Ligands -- A. Classification -- B. The preparation of olefin-transition metal complexes -- C. A molecular orbital description of the bonding in organo-metallic complexes -- D. A description of the bonding of 2-electron ligands to transition metals -- E. General comments of 2-electron ligands -- F. Particular complexes of metals with 2-electron ligands -- 2. Three-Electron Ligands -- A. Preparation of ?-enyl complexes -- B. The structure of ?-enyl complexes -- C. The ?-allyl metal bond -- D. Dynamic equilibria in allyl complexes -- E. The chemistry of particular ?-enyl complexes -- 3. Four-Electron Ligands -- A. Some differences between unconjugated and conjugated olefin ligands -- B. The bonding of 4-electron ligands to transition metals -- C. Particular studies -- 4. Five-Electron Ligands -- A. Cyclopentadienyl metal complexes -- B. ?-Cyclopentadienyl transition metal complexes -- C. Cyclopentadienide transition metal complexes -- D. The bonding in mono-?-cyclopentadienyl transition metal complexes -- E. ?-Cyclopentadienyl carbonyl complexes -- F. ?-Cyclopentadienyl nitrosyl complexes -- G. Brief notes on binuclear ?-cyclopentadienyl complexes containing bridging ligands -- H. ?-Cyclopentadienyl hydride complexes -- I. ?-Cyclopentadienyl halides and oxides -- J. Other 5-electron ligands -- K. The organic chemistry of ?-cyclopentadienyl transition metal complexes -- L. Some particular reactions -- 5. Six-Electron Ligands -- A. Arene transition metal complexes -- (a) Preparation -- B. Olefin 6-electron ligands -- C. Transition metal complexes containing ?-bonded heterocyclic ligands -- 6. Seven-Electron Ligands Mixed Sandwich Complexes Related Azulene Derivatives and Cyclo-Octatetraene Complexes -- A. 7-Electron ligands.-B. Mixed sandwich complexes -- C. Metal complexes formed from azulenes -- D. Cyclo-octatetraene complexes -- 7. One-Electron Ligands -- I.1. Hydrocarbon alkyl and aryl complexes -- I.2 Transition metal-acyl complexes -- I.3. ?-Cyclopentadienyl complexes -- II. Transition metal fluorocarbon complexes -- III. Transition metal acetytides and alkynyls -- 8. Organometallic Complexes Formed From Acetylenes -- A. Monoacetylene, mononuclear complexes: acetylenes as 2-elec-tron ligands -- B. Monoacetylene binuclear complexes: acetylenes as 4-electron ligands -- C. Monoacetylene trinuclear complexes -- D. Monoacetylene tetranuclear complexes -- E. Bis-acetylene mononuclear complexes -- F. Bis-acetylene trinuclear complexes -- G. Tris-acetylene mononuclear complexes -- H. Tris-acetylene binuclear complexes -- I. Miscellaneous -- 9. The Role of Organotransition Metal Complexes in Some Catalytic Reactions -- A. Some chemistry of transition metal hydride complexes -- B. Some catalytic reactions which involve hydrogen transfer: isomerization reactions -- C. Homogeneous hydrogenation of olefins and acetylenes -- D. Some dimerization oligomerization and polymerization reactions of olefins and acetylenes -- E. Hydroformylation and related carhonylation reactions -- F. Some general comments on the relationship between heterogeneous and homogeneous transition metal catalysts -- G. Miscellaneous -- Author -- Subject -- Crystal Structures>.
Özet, vb.
to thank Messrs J. R. Sanders, W. E. Lindsell and M. G. Swanwick for helping to check the text and references and prepare indexes. Finally, I should like to thank my wife for the very considerable assis­ tance she has given me in the writing and production of this book. M. L. H. G. Contents Preface to the Third Edition, Volume Two Page v INTRODUCTION TO VOLUME TWO I Oassification I The IS-electron rule 2 (i) The basis of the I8-electron rule p. 4, (ii) Exceptions to the I8-electron rule p. 5 1. TWO-ELECTRON LIGANDS 7 A. Classification 7 B. The preparation of olefin-transition metal complexes 7 (a) Displacement of solvent ligands p. 9, (b) Preparations from metal carbonyls p. 9, (c) Less common preparative routes p. 11, Reductive olefination method p. 12 C. A molecular orbital description of the bonding in orga- metallic complexes 13 (a) General comments p. 13, (b) Symmetry considerations p. 13, (c) Energies of the molecular orbitals p. 14 D. A description of the bonding of 2-electron ligands to transition metals 14 E. General comments of 2-electron ligands 19 (a) Infrared studies p. 20, (b) Effect of olefin substituents p. 21, (c) The rotation of ethylene about the ligand-metal bond p. 22, (d) Chemical properties p. 23 F. Particular complexes of metals with 2-electron ligands 25 (a) Copper, silver and gold p. 25, Complexes with benzene p. 28, (b) Nickel, palladium and platinum p.
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